Bis[bis(1-ethylbenzimidazol-2-ylmethyl) ether]cobalt(II) dipicrate dimethylformamide disolvate
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چکیده
منابع مشابه
Bis[1,3-bis(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethylformamide disolvate
In the title compound, [Zn(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Zn(II) ion is coordinated in a distorted octa-hedral environment involving four equatorial N atoms and two O atoms in axial sites. The dihedral angles between the benzimidazole ring system and the phenyl rings in each of the benzyl-benzimidazole units are 78.56 (12), 81.68 (11), 75.76 (10) and 85.78 (9)°. In t...
متن کاملAqua[1,3-bis(benzimidazol-2-yl)-2-oxapropane]diethanolmanganese(II) dipicrate ethanol disolvate
In the title complex, [Mn(C(16)H(14)N(4)O)(C(2)H(5)OH)(2)(H(2)O)](C(6)H(2)N(3)O(7))(2)·2C(2)H(5)OH, the Mn(II) ion is in a distorted octa-hedral coordination environment, defined by an MnN(2)O(4) donor set. The 1,3-bis-(benz-imid-azol-2-yl)-2-oxapropane ligand is tridentate. In the crystal structure, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the components into a three-dimensional net...
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In the title compound, [Cd(C(20)H(22)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis-(1-ethyl-1H-benzimid-azol-2-yl)-2-oxapropane ligands in a distorted octa-hedral environment.
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The crystal structure of the title compound, [Cd(C(29)H(29)N(5))(2)](C(6)H(2)N(3)O(7))(2), consists of Cd(II) complex cations and picrate anions. In the complex cation, the Cd(II) ion is chelated by two bis-(1-allyl-benzimidazol-2-ylmeth-yl)benzyl-amine (babb) ligands in a distorted octa-hedral geometry. Extensive C-H⋯O hydrogen bonding occurs between cations and anions in the crystal structure.
متن کاملAqua(dimethylformamide){tris[(1-methyl-1H-benzimidazol-2-yl)methyl]amine}nickel(II) dipicrate
In the title complex, [Ni(C(27)H(27)N(7))(C(3)H(7)NO)(H(2)O)](C(6)H(2)N(3)O(7))(2), the Ni(II) ion is coordinated in a slightly distorted octa-hedral coordination evironment by an NiN(4)O(2) ligand set. The tris-(N-methyl-benzimidazol-2-ylmeth-yl)amine ligand is in a tetra-dentate mode while a coordinated water molecule and a dimethyl-formamide ligand complete the coordination. In the crystal s...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809035934